A new solar-induced direct biomass-to-electricity hybrid fuel cell can
operate on fuels as varied as powdered wood. The fuel cell
relies on a polyoxometalate (POM) catalyst (shown in the vials)
which changes color as it reacts with light.
Now, researchers at the Georgia Institute of Technology have developed a new type of low-temperature fuel cell that directly converts biomass to electricity with assistance from a catalyst activated by solar or thermal energy. The hybrid fuel cell can use a wide variety of biomass sources, including starch, cellulose, lignin -- and even switchgrass, powdered wood, algae and waste from poultry processing.
The device could be used in small-scale units to provide electricity for developing nations, as well as for larger facilities to provide power where significant quantities of biomass are available.
The challenge for biomass fuel cells is that the carbon-carbon bonds of the biomass -- a natural polymer -- cannot be easily broken down by conventional catalysts, including expensive precious metals, Deng noted. To overcome that challenge, scientists have developed microbial fuel cells in which microbes or enzymes break down the biomass. But that process has many drawbacks: power output from such cells is limited, microbes or enzymes can only selectively break down certain types of biomass, and the microbial system can be deactivated by many factors.
The system provides major advantages, including combining the photochemical and solar-thermal biomass degradation in a single chemical process, leading to high solar conversion and effective biomass degradation. It also does not use expensive noble metals as anode catalysts because the fuel oxidation reactions are catalyzed by the POM in solution. Finally, because the POM is chemically stable, the hybrid fuel cell can use unpurified polymeric biomass without concern for poisoning noble metal anodes.
The system can use soluble biomass, or organic materials suspended in a liquid. In experiments, the fuel cell operated for as long as 20 hours, indicating that the POM catalyst can be re-used without further treatment.
Source : Science daily
Now, researchers at the Georgia Institute of Technology have developed a new type of low-temperature fuel cell that directly converts biomass to electricity with assistance from a catalyst activated by solar or thermal energy. The hybrid fuel cell can use a wide variety of biomass sources, including starch, cellulose, lignin -- and even switchgrass, powdered wood, algae and waste from poultry processing.
The device could be used in small-scale units to provide electricity for developing nations, as well as for larger facilities to provide power where significant quantities of biomass are available.
The challenge for biomass fuel cells is that the carbon-carbon bonds of the biomass -- a natural polymer -- cannot be easily broken down by conventional catalysts, including expensive precious metals, Deng noted. To overcome that challenge, scientists have developed microbial fuel cells in which microbes or enzymes break down the biomass. But that process has many drawbacks: power output from such cells is limited, microbes or enzymes can only selectively break down certain types of biomass, and the microbial system can be deactivated by many factors.
The system provides major advantages, including combining the photochemical and solar-thermal biomass degradation in a single chemical process, leading to high solar conversion and effective biomass degradation. It also does not use expensive noble metals as anode catalysts because the fuel oxidation reactions are catalyzed by the POM in solution. Finally, because the POM is chemically stable, the hybrid fuel cell can use unpurified polymeric biomass without concern for poisoning noble metal anodes.
The system can use soluble biomass, or organic materials suspended in a liquid. In experiments, the fuel cell operated for as long as 20 hours, indicating that the POM catalyst can be re-used without further treatment.
Source : Science daily
